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Keywords
- Cavitation; Corrosion; Laser remelting; Self-fluxing alloys; Stellite 6 (1)
- Stellite 6; HVOF-spraying; Laser remelting; Cavitation erosion; Coatings (1)
- additive manufacturing; polylactic acid (PLA); fused filament fabrication (FFF); fused deposition modeling (FDM); printing temperature; filament color; dimensional accuracy; tensile strength; friction performance; wear (1)
- corrosion; self-fluxing alloys; NiCrBSi; WC-12Co; cavitation; hard metals (1)
- fused deposition modeling (FDM); fused filament fabrication (FFF); polylactic acid (PLA); layer height; layer thickness; filament color; PLA color; dimensional accuracy; tensile strength (1)
Optimization of the laser remelting process for HVOF-sprayed Stellite 6 wear resistant coatings
(2016)
Cobalt base alloys are used in all industrial areas due to their excellent wear resistance. Several studies have shown that Stellite 6 coatings are suitable not only for protection against sliding wear, but also in case of exposure to impact loading. In this respect, a possible application is the protection of hydropower plant components affected by cavitation. The main problem in connection with Stellite 6 is the deposition procedure of the protective layers, both welding and thermal spraying techniques requesting special measures in order to prevent the brittleness of the coating. In this study, Stellite 6 layers were HVOF thermally sprayed on a martensitic 13-4 stainless steel substrate, as usually used for hydraulic machinery components. In order to improve the microstructure of the HVOF-sprayed coatings and their adhesion to the substrate, laser remelting was applied, using a TRUMPF Laser type HL 124P LCU and different working parameters. The microstructure of the coatings, obtained for various remelting conditions, was evaluated by light microscopy, showing the optimal value of the pulse power, which provided a homogenous Stellite 6 layer with good adhesion to the substrate.
This paper aims to compare cobalt-based (type Stellite 6) and nickel-based self-fluxing alloys (type NiCrBSiMo) regarding both their cavitation erosion resistance and corrosion resistance. The two types of protective layers were thermally sprayed onto a substrate of martensitic stainless steel. In order to improve the layers' characteristics and their metallurgical bonding to the substrate, the Stellite 6 coating was laser remelted, while the NiCrBSiMo coating was treated by flame fusion. The cavitation erosion resistance of the two materials was evaluated by measurements of the mean depth of erosion developed during a testing period of 165 minutes, using a 20 kHz ultrasonic vibrator at a peak-to-peak amplitude of 50 μm. In addition, the corrosion resistance of the layers was assessed by potentiodynamic corrosion tests carried out in H2SO4 + NaCl solution at room temperature, using calomel as reference electrode. In order to highlight the differences regarding the behaviour of the two protective materials, the authors also carried out microstructural investigations of the layers before and after exposure to cavitation and corrosion. The investigations showed that both types of layers can provide improved protection of the martensitic stainless steel substrate against cavitation, whilst the NiCrBSiMo coating additionally confers significantly increased resistance to corrosion.
Flame-sprayed NiCrBSi/WC-12Co composite coatings were deposited in different ratios on the surface of stainless steel. Oxyacetylene flame remelting treatment was applied to surfaces for refinement of the morphology of the layers and improvement of the coating/substrate adhesion.
The performance of the coated specimens to cavitation erosion and electrochemical corrosion was evaluated by an ultrasonic vibratory method and, respectively, by polarization measurements. The microstructure was investigated by means of scanning electron microscopy (SEM) combined with energy dispersive X-ray analysis (EDX). The obtained results demonstrated that the addition of 15 wt.% WC-12Co to the self-fluxing alloy improves the resistance to cavitation erosion (the terminal erosion rate (Vs) decreased with 15% related to that of the NiCrBSi coating) without influencing the good corrosion resistance in NaCl solution. However, a further increase in WC-Co content led to a deterioration of these coating properties (the Vs has doubled related to that of the NiCrBSi coating).
Moreover, the corrosion behavior of the latter composite coating was negatively influenced, a fact confirmed by increased values for the corrosion current density (icorr). Based on the achieved experimental results, one may summarize that NiCrBSi/WC-Co composite coatings are able to increase the life cycle of expensive, high-performance components exposed to severe cavitation conditions.
The printing variable least addressed in previous research aiming to reveal the effect of the FFF process parameters on the printed PLA part’s quality and properties is the filament color. Moreover, the color of the PLA, as well as its manufacturer, are rarely mentioned when the experimental conditions for the printing of the samples are described, although current existing data reveal that their influence on the final characteristics of the print should not be neglected. In order to point out the importance of this influential parameter, a natural and a black-colored PLA filament, produced by the same manufacturer, were selected. The dimensional accuracy, tensile strength, and friction properties of the samples were analyzed and compared for printing temperatures ranging from 200 C up to 240 C. The experimental results clearly showed different characteristics depending on the polymer color of samples printed under the same conditions. Therefore, the optimization of the FFF process parameters for the 3D-printing of PLA should always start with the proper selection of the type of the PLA material, regarding both its color and the fabricant.
Among the FDM process variables, one of the less addressed in previous research is the filament color. Moreover, if not explicitly targeted, the filament color is usually not even mentioned.
Aiming to point out if, and to what extent, the color of the PLA filaments influences the dimensional precision and the mechanical strength of FDM prints, the authors of the present research carried out experiments on tensile specimens. The variable parameters were the layer height (0.05 mm, 0.10 mm, 0.15 mm, 0.20 mm) and the material color (natural, black, red, grey). The experimental results clearly showed that the filament color is an influential factor for the dimensional accuracy as well as for the tensile strength of the FDM printed PLA parts. Moreover, the two way ANOVA test performed revealed that the strongest effect on the tensile strength was exerted by the PLA color (2 = 97.3%), followed by the layer height (2 = 85.5%) and the interaction between the PLA color and the layer height (2 = 80.0%). Under the same printing conditions, the best dimensional accuracy was ensured by the black PLA (0.17% width deviations, respectively 5.48% height deviations), whilst the grey PLA showed the highest ultimate tensile strength values (between 57.10 MPa and 59.82 MPa).