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Handbuch Sporttourismus
(2016)
A quantum two-level system immersed in a sub-Ohmic bath experiences enhanced low-frequency quantum statistical fluctuations which render the nonequilibrium quantum dynamics highly non-Markovian. Upon using the numerically exact time-evolving matrix product operator approach, we investigate the phase diagram of the polarization dynamics. In addition to the known phases of damped coherent oscillatory dynamics and overdamped decay, we identify a new third region in the phase diagram for strong coupling showing an aperiodic behavior. We determine the corresponding phase boundaries. The dynamics of the quantum two-state system herein is not coherent by itself but slaved to the oscillatory bath dynamics.
There is a strongly held belief that if companies can direct their marketing activities to improve customer attitudes and intentions, it will impact on purchase behaviors. Departing from complementary yet sometimes conflicting findings of the current literature, we intend to contribute to the literature by answering two related questions. First, we investigate drivers of loyalty intention over time, and by so doing try to better understand loyalty formation. Second, once we understand loyalty formation, we assess the impact of loyalty on different aspects of purchase behavior, considering temporal effects. Therefore, we develop a consumption-system model which assumes that perceptions, intention, and the impact of perceptions and intention on behavior in one period serve as anchors for the same constructs in a subsequent period, implying a pattern of repeated consumption over time.
Using 3SLS regression analysis, results of a large-scale study using survey data from a sample of 2,478 customers from two points in time and purchase data gathered over a 30-month period suggest interesting findings on the two aforementioned questions:
Considering the first question, we find strong support for customer equity drivers directly influencing loyalty. Moreover, we see evidence for loyalty formation as a consumption-system as equity drivers and loyalty intention of one period are significant predictors of the same constructs in the next period.
Addressing the second research question is less straightforward. We find a significant impact of loyalty intention only for purchase frequency, but not for future sales and average receipt. This suggests that in a retailing context, the amount spent depends to a larger extent on actual needs and not on loyalty intention. Loyalty intention seems to be a more appropriate lead indicator for the frequency of store visits. For most categories, repurchase intention will not necessarily be related to higher sales. On the contrary, higher future sales are more likely to depend on the retailer’s ability to cross- and up-sell to its customers. In all, we need to acknowledge that the strongest predictor of future behavior is, in fact, past behavior.
These results question some of the strongly held beliefs of relationship marketing and its impact on actual behavior. Effects might not be as simple as they appear at first, i.e., temporal interplay between constructs. Moreover, it seems that inertia is more important than some marketing research tends to acknowledge. We would therefore suggest a more detailed investigation of customers’ initial choice behavior. If, in fact, inertia is the driving force behind purchase behavior, companies need to augment their emphasis on increasing initial customer contact and, accordingly, on initial product trial. This is somewhat counter-intuitive from a relationship marketing perspective, because that stream of research largely suggests the advantage of retaining customers rather than acquiring new ones. While we are not denying the importance of customer retention, it seems that companies are already fairly successful in doing so – the strong inertia effect confirms that. Hence, customer retention might not be the best strategy to differentiate in the market. Perhaps companies can better differentiate by excelling in customer acquisition. This, however, would have a significant impact on how marketing budgets should be spent by companies trying to reach sustained success. It might be time for re-balancing customer acquisition and customer retention.
We propose a quantum-mechanical model to calculate the current through a single molecular junction immersed in a solvent and surrounded by a thin shell of bound water under an applied ac voltage. The solvent plus hydration shell are captured by a dielectric continuum model for which the resulting spectral density is determined. Here the dielectric properties, e.g., the Debye relaxation time and the dielectric constant, of the bulk solvent and the hydration shell as well as the shell thickness directly enter. We determine the charge current through the molecular junction under an ac voltage in the sequential tunneling regime where we solve a quantum master equation by a real-time diagrammatic technique. Interestingly, the Fourier components of the charge current show an exponential-like decline when the hydration shell thickness increases. Finally, we apply our findings to binary solvent mixtures with varying volume fractions and find that the current is highly sensitive to both the hydration shell thickness as well as the volume fraction of the solvent mixture, giving rise to possible applications as shell and concentration sensors on the molecular scale.
Intercultural Communication Competence: Implications for Learning and Teaching in a Globalized World
(2007)
Interkulturelle Kompetenz
(2021)
We study the impact of underdamped intramolecular vibrational modes on the efficiency of the excitation energy transfer in a dimer in which each state is coupled to its own underdamped vibrational mode and, in addition, to a continuous background of environmental modes. For this, we use the numerically exact hierarchy equation of motion approach. We determine the quantum yield and the transfer time in dependence of the vibronic coupling strength, and in dependence of the damping of the incoherent background. Moreover, we tune the vibrational frequencies out of resonance with the excitonic energy gap. We show that the quantum yield is enhanced by up to 10% when the vibrational frequency of the donor is larger than at the acceptor. The vibronic energy eigenstates of the acceptor acquire then an increased density of states, which leads to a higher occupation probability of the acceptor in thermal equilibrium. We can conclude that an underdamped vibrational mode which is weakly coupled to the dimer fuels a faster transfer of excitation energy, illustrating that long-lived vibrations can, in principle, enhance energy transfer, without involving long-lived electronic coherence.
Iran ans Netz
(2002)
"IRAN im Informationszeitalter" beschreibt ausgesuchte Software, skizziert den IT-Status quo im Iran und informiert Studierende, Lehrende, Manager, IT-Praktiker und interkulturell Interessierte über ein Land im Brennpunkt Mittlerer Osten.
Der vorliegende zweite Band der Reihe "Interkulturelles Medienmanagement" erläutert in komprimierter, leicht verständlicher Form eine Auswahl aktueller, hierzulande etablierter IT-Anwendungen. Gezeigt wird, wie im Iran mit Groupware, Data Warehouse, E-Learning, Wissensmanagement und K-Pool experimentiert wird, und wie diese Systeme in kleinen Schritten Einzug halten.
Die Bedingungen, in denen sich der unaufhaltsame Fortschritt vollzieht, sind in den Kapiteln über islamische Religion, Konstruktion des Staates und Hierarchie der Mullahs beschrieben. Eindrücke vom Land vermitteln die Reportagen "Die weite Fahrt zum Arbeitsplatz", "Von der Hauptstadt zum Schrein des 8. Imam" und "Teheran Impressionen".
Von Bruchlinien zwischen den Kulturen und Möglichkeiten, diese zu überbrücken, handelt das Kapitel "Von Klüften und Brücken". Es geht um Analysen, Modelle, Methoden und Strategien für die Entwicklung von Handlungskompetenz.
Streiflichter illustrieren die bunte Szenerie, in der sich Studierende im Iran bewegen.
Jasminduft für das Audimax
(2015)
Feste und Feiern bereichern das öffentliche Leben in der Kommune. Die Kirmes ist ein Ort der Zusammenkunft und eröffnet die Möglichkeit zur temporären Beglückung. Die Teilhabe an der Kirmes ist prinzipiell allen möglich und ist sowohl ein außeralltägliches Ereignis als auch ein populäres Vergnügen, ohne das für eine gelingende Teilhabe besondere Kenntnisse oder Fähigkeiten vorausgesetzt werden.
„Hinter den Kulissen“ erfordert die Veranstaltung einer Kirmes einen mehrmonatigen Aufwand, der mit Personal- und Sachkosten verbunden ist. Ob sich eine Kommune „ihre“ Kirmes weiterhin leisten wird, hängt nicht nur von ihren personellen und finanziellen Ressourcen ab, sondern auch von der Ausstrahlung der Veranstaltung und der Nach-frage potentieller BesucherInnen.
Um die Fragen zur Bedeutung, Organisation und Perspektive (bis zu einem gewissen Grade) zu beantworten, wurden die großen und kleinen Kirmesveranstaltungen der Städte und Gemeinden im Kreis Borken untersucht. Aus den Ergebnissen leiten sich konzeptionelle Grundlagen ab und Einschätzungen auf die weiteren Perspektiven
Klasse, Lebensstil und Kulturindustrie oder: Warum wir meinen sollen, Golf spielen zu wollen!
(2006)
We derive a Magnus expansion for a frequency chirped quantum two-level system. We obtain a time-independent effective Hamiltonian which generates a stroboscopic time evolution. At lowest order the according dynamics is identical to results from using a rotating wave approximation. We determine, furthermore, also the next higher-order corrections within our expansion scheme in correspondence to the Bloch-Siegert shifts for harmonically driven systems. Importantly, our scheme can be extended to more complicated systems, i.e., even many-body systems.
Jeder angehende Ökonom muss gesamtwirtschaftliche Zusammenhänge verstehen und deuten können. Dieses Buch vermittelt dafür das notwendige Know-how. Die Autoren beleuchten die Volkswirtschaftlichen Gesamtrechnungen, das Phänomen Wirtschaftswachstum, den Arbeitsmarkt und die monetären Märkte.
Darauf aufbauend stellen sie zentrale Modelle der Volkswirtschaftslehre dar und wenden sie auf wirtschaftspolitische Problemstellungen an. Jedes Kapitel wird durch Lernziele eingeleitet und durch eine kompakte Zusammenfassung abgeschlossen. Im Text finden sich Fallbeispiele, Abbildungen und hervorgehobene Definitionen.
Zahlreiche Übungsaufgaben ermöglichen die Überprüfung und Vertiefung des Erlernten. Das Buch richtet sich an Studierende der Betriebs- und Volkswirtschaftslehre an Fachhochschulen und Universitäten. Fazit: Durch seinen didaktischen Aufbau und den zahlreichen anschaulichen Beispielen eignet sich dieses Buch hervorragend als vorlesungsbegleitende Lektüre und zur Prüfungsvorbereitung.
Menschen, Technik, Götter
(2002)
Mentoring
(2001)
Multimedia im Höhentest
(2001)
Betriebliches Talentmanagement als Rekrutierungsstrategie wird in der jüngeren Literatur (auch) unter ethischen Gesichtspunkten kritisch diskutiert. Ich suche daher nach soziologisch und wirtschaftswissenschaftlich fundierten Konzepten für ein nicht-elitäres, inkludierendes Talentmanagement, das auch der sozialen Verantwortung von Unternehmen und Bildungseinrichtungen gerecht wird. Dazu wird der „Capability-Ansatz“ herangezogen, und es werden die Beziehungen zwischen (nicht-elitärem) Talentmanagement und Diversity-Management (DiM) dargelegt. Ein Praxisfall aus der Hochschullandschaft wird präsentiert und aus Sicht der Entwicklung von „Capabilities“ untersucht.
Commonly, nanosystems are characterized by their response to time-dependent external fields in the presence of inevitable environmental fluctuations. The direct impact of the external driving on the environment is generally neglected. While this approach is satisfactory for macroscopic systems, on the nanoscale, an interaction of external fields with the environment is often unavoidable on principle. We extend the standard linear response theory of quantum dissipative systems to strongly driven baths. Significant modifications are found for two paradigm examples. First, we evaluate the polarizability of a molecule immersed in a strongly polarizable medium that responds to terahertz radiation. We find an increase of the molecular polarizability by about 30%. Second, we determine the response of a semiconductor quantum dot in close proximity to a metallic nanoparticle. Both are placed in a polarizable medium and exposed to electromagnetic irradiation. We show that the response of the quantum dot is qualitatively modified by the driven nanoparticle, including the generation of an additional channel of stimulated emission.
Environmental noise leads to dephasing and relaxation in a quantum system. Often, a rigorous treatment of multiple noise sources within a system-bath approach is not possible. We discuss the influence of environmental fluctuations on a quantum system whose dynamics is dephasing already due to a phenomenologically treated additional noise source. For this situation, we develop a path-integral approach, which allows us to treat the system-environment coupling in a numerically exact way, and additionally we extend standard perturbative approaches. We observe strong deviations between the numerically exact and the perturbative results even for weak system-bath coupling. This shows that standard perturbative approaches fail for additional, even weak, system-bath couplings if the system dynamics is already dissipative.
Recent experimental results showing atypical nonlinear absorption and marked deviations from well known universality in the low temperature acoustic and dielectric losses in amorphous solids prove the need for improving the understanding of the nature of two-level systems (TLSs) in these materials. Here we suggest the study of TLSs focused on their properties which are nonuniversal. Our theoretical analysis shows that the standard tunneling model and the recently suggested two-TLS model provide markedly different predictions for the experimental outcome of these studies. Our results may be directly tested in disordered lattices, e.g KBr:CN, where there is ample theoretical support for the validity of the two-TLS model, as well as in amorphous solids. Verification of our results in the latter will significantly enhance understanding of the nature of TLSs in amorphous solids, and the ability to manipulate them and reduce their destructive effect in various cutting edge applications including superconducting qubits.
Plädoyer für eine Diversifizierung des unternehmerischen Leitbildes in Forschung und Beratung
(2012)
Seit den 1980er Jahren erlangt der Vertrauensbegriff im organisationalen Kontext eine immer größer werdende Bedeutung. Dennoch sind die Einflussfaktoren, welche auf die unterschiedlichen Arten des organisationalen Vertrauens wirken, weitestgehend unbekannt. Daher sollen in diesem Beitrag durch qualitative und quantitative Methoden zunächst die unterschiedlichen organisationalen Rahmenbedingungen zweier verschiedeneer sozialer Dienstleister eufgezeigt werden. In einem weiteren Schritt sollen mittels quantitativer Methoden die Einflussfaktoren auf die unterschiedlichen Formen des Vertrauens in Organisationen dargestellt sowie Konsequenzen für die praktische Arbeit abgeleitet werden.
Quantum systems are typically subject to various environmental noise sources. Treating these environmental disturbances with a system-bath approach beyond weak coupling, one must refer to numerical methods as, for example, the numerically exact quasi-adiabatic path integral approach. This approach, however, cannot treat baths which couple to the system via operators, which do not commute. We extend the quasi-adiabatic path integral approach by determining the time discrete influence functional for such non-commuting fluctuations and by modifying the propagation scheme accordingly. We test the extended quasi-adiabatic path integral approach by determining the time evolution of a quantum two-level system coupled to two independent baths via non-commuting operators. We show that the convergent results can be obtained and agreement with the analytical weak coupling results is achieved in the respective limits.
Rationale Klimaschutzpolitik
(2008)
Selbst und Zeitmanagement. Optionen erkennen. Selbstverantwortlich handeln. In Netzwerken agieren
(2004)
Sensortechnik
(1999)
We propose a quantum-mechanical model to calculate the nonlinear differential conductance of a single molecular junction immersed in a solvent, either in pure form or as a binary mixture with varying volume fraction. The solvent mixture is captured by a dielectric continuum model for which the resulting spectral density is determined within the Gladstone-Dale approach. The conductance of the molecular junction is calculated by a real-time diagrammatic technique. We find a strong variation of the conductance maximum for varying volume fraction of the solvent mixture. Importantly, the calculated molecular nonlinear conductance shows a very good agreement with experimentally measured data for common molecular junctions in various polar solvent mixtures.
When a hydrophilic solute in water is suddenly turned into a hydrophobic species, for instance, by photoionization, a layer of hydrated water molecules forms around the solute on a time scale of a few picoseconds. We study the dynamic buildup of the hydration shell around a hydrophobic solute on the basis of a time-dependent dielectric continuum model. Information about the solvent is spectroscopically extracted from the relaxation dynamics of a test dipole inside a static Onsager sphere in the nonequilibrium solvent. The growth process is described phenomenologically within two approaches. First, we consider a time-dependent thickness of the hydration layer that grows from zero to a finite value over a finite time. Second, we assume a time-dependent complex permittivity within a finite layer region around the Onsager sphere. The layer is modeled as a continuous dielectric with a much slower fluctuation dynamics. We find a time-dependent frequency shift down to the blue of the resonant absorption of the dipole, together with a dynamically decreasing line width, as compared to bulk water. The blue shift reflects the work performed against the hydrogen-bonded network of the bulk solvent and is a directly measurable quantity. Our results are in agreement with an experiment on the hydrophobic solvation of iodine in water.
Der Beitrag geht (1) auf zentrale Aspekte neoliberaler Wirtschaftspolitik ein, (2) damit verbundene branchenspezifische Strategien und Ideologiemuster sowie (3) auf individuell übernommene Denkfiguren zur marktförmigen Selbstoptimierung. Abschließend werden (4) Alternativen auf kommunaler, wirtschafts- und sportpolitischer Ebene aufgezeigt.
Sport und Tourismus
(2007)
Insofern sich Städte als „Unternehmen“ begreifen (sollen), werden Sportgroßveranstaltungen als „Standortfaktor“ benutzt, so dass die Förderung des Sports und seiner kulturellen Potentiale in den Hintergrund gedrängt wird. Dadurch ist aber die Zustimmung zu den großen Veranstaltungen des Sports nicht mehr ungeteilt. Zusätzlich besteht die Problematik, wie viel sich Städte die von ihnen (mit)ausgerichteten Sportgroßveranstaltungen etwas kosten lassen wollen, bzw. überhaupt noch können.
Mit einer interdisziplinären und kritischen Herangehensweise richtet der Band seinen Blick auf die Felder der Verwaltung, der Ökonomie und Politik sowie auf den Sport als kulturelle Praxis. Aus dieser Perspektive zeigt das Buch sport- und wirtschaftspolitische Orientierungen für einen angemessenen und konzeptionellen Umgang mit Sportgroßveranstaltungen auf.
Der Inhalt
• Kommunale Daseinsvorsorge und Sportgroßveranstaltungen
• Zentrale Aspekte und Wandel der Wirtschaftspolitik
• Die Stadt als „Unternehmen“
• Sportgroßveranstaltungen zwischen Kultur und weichem Standortfaktor
• Ökonomische Effekte und Defekte: sorgfältig, „kreativ“ oder unlauter berechnet
• Exkurs: Grand Départ der Tour de France
• Exkurs: Vor allem (zu viel) Fußball
• Konzepte, Handlungsmöglichkeiten, Perspektiven
Die Zielgruppen
• Lokale und regionale Akteure aus Politik und Verwaltung
• Akteure der Sportverbände und Zivilgesellschaft
• Lehrende und Studierende der Sportsoziologie und -ökonomie
Sporttourismus
(2014)
Neuroscientists want to inspect the data their simulations are producing while these are still running. This will on the one hand save them time waiting for results and therefore insight. On the other, it will allow for more efficient use of CPU time if the simulations are being run on supercomputers. If they had access to the data being generated, neuroscientists could monitor it and take counter-actions, e.g., parameter adjustments, should the simulation deviate too much from in-vivo observations or get stuck.
As a first step toward this goal, we devise an in situ pipeline tailored to the neuroscientific use case. It is capable of recording and transferring simulation data to an analysis/visualization process, while the simulation is still running. The developed libraries are made publicly available as open source projects. We provide a proof-of-concept integration, coupling the neuronal simulator NEST to basic 2D and 3D visualization.
The two-state two-path model is introduced as a minimized model to describe the quantum dynamics of an electronic wave packet in the vicinity of a conical intersection. It involves two electronic potential energy surfaces each of which hosts a pair of quasi-classical trajectories over which the wave packet is assumed to be delocalized. When both trajectories evolve dynamically either diabatically or adiabatically, the full wave packet dynamics shows only features of the dynamics around avoided level crossings in the vicinity of the conical intersection. When one trajectory evolves adiabatically whereas the other trajectory follows a diabatic evolution, quantum mechanical interference of the wave packet components on each path generates Stueckelberg oscillations in the transition probability. These are surprisingly robust against a dissipative environment and, thus, should be a marker for conical intersections.
The two-state two-path model is introduced as a minimized model to describe the quantum dynamics of an electronic wave packet in the vicinity of a conical intersection. It involves two electronic potential energy surfaces each of which hosts a pair of quasi-classical trajectories over which the wave packet is assumed to be delocalized. When both trajectories evolve dynamically either diabatically or adiabatically, the full wave packet dynamics shows only features of the dynamics around avoided level crossings in the vicinity of the conical intersection. When one trajectory evolves adiabatically whereas the other trajectory follows a diabatic evolution, quantum mechanical interference of the wave packet components on each path generates Stueckelberg oscillations in the transition probability. These are surprisingly robust against a dissipative environment and, thus, should be a marker for conical intersections.
We study the nonequilibrium dynamics of a quantum system under the influence of two noncommuting fluctuation sources, i.e., purely dephasing fluctuations and relaxational fluctuations. We find that increasing purely dephasing fluctuations suppress increasing relaxation in the quantum system. This effect is further enhanced when both fluctuation sources are fully correlated. These effects arise for medium to strong primary fluctuations already when the secondary fluctuations are weak due to their noncommuting coupling to the quantum system. Dephasing, in contrast, is increased by increasing any of the two fluctuations. Fully correlated fluctuations result in overdamping at much lower system-bath coupling than uncorrelated noncommuting fluctuations. In total, we observe that treating subdominant secondary environmental fluctuations perturbatively leads, as neglecting them, to erroneous conclusions.
Tunneling two-level systems (TLSs) are ubiquitous in amorphous solids, and form a major source of noise in systems such as nano-mechanical oscillators, single electron transistors, and superconducting qubits. Occurance of defect tunneling despite their coupling to phonons is viewed as a hallmark of weak defect-phonon coupling. This is since strong coupling to phonons results in significant phonon dressing and suppresses tunneling in two-level tunneling defects effectively. Here we determine the dynamics of a tunneling defect in a crystal strongly coupled to phonons incorporating the full 3D geometry in our description. Wefind that inversion symmetric tunneling is not dressed by phonons whereas other tunneling pathways are dressed by phonons and, thus, are suppressed by strong defect-phonon coupling. We provide the linear acoustic and dielectric response functions for a tunneling defect in a crystal for strong defect-phonon coupling. This allows direct experimental determination of the defect-phonon coupling. The singling out of inversion-symmetric tunneling states in single tunneling defects is complementary to their dominance of the low energy excitations in strongly disordered solids as a result of inter-defect interactions for large defect concentrations. This suggests that inversion symmetric TLSs play a unique role in the low energy properties of disordered solids.
In der Diskussion um Strategien zum Abbau der Arbeitslosigkeit ist der Dienstleistungssektor zum Hoffnungsträger geworden. Viele sehen das Dienstleistungsgewerbe schon als Motor des wirtschaftlichen Wachstums in der Bundesrepublik an. Allerdings übersieht diese These wechselseitige Abhängigkeiten zwischen sekundärem und tertiärem Sektor. Die empirische Analyse für den Regierungsbezirk Münster verdeutlicht, daß die Vorleistungsbeziehungen zwischen beiden Sektoren eine bedeutende Rolle spielen. Insofern hängen die Beschäftigungserfolge im Dienstleistungssektor auch von der Wettbewerbsfähigkeit der regionalen Industrie ab. Eine Förderung der Dienstleistungsbereiche ohne entsprechende Pflege der industriellen Basis erweist sich daher als fragwürdige Strategie.
We show that strong non-Markovian effects can be revealed by the steady-state two-dimensional (2D) photon echo spectra at asymptotic waiting times. For this, we use a simple dimer toy model that is strongly coupled to a harmonic bath with parameters typical for photoactive biomolecules. We calculate the 2D photon echo spectra employing both the numerically exact hierarchy equation of motion and the quasiadiabatic path integral approach and compare these results with approximate results from a time-nonlocal quantum master equation approach. While the latter correctly reproduces the exact population dynamics at long times, it fails at the same time to correctly describe the 2D photon echo spectra at long waiting times. The differences show that non-Markovian effects are much more important for the steady-state 2D photon echoes than for the equilibrium populations. Thus, accurate theoretical descriptions of the energy transfer dynamics in biomolecular complexes have to be based on numerically exact simulations of the environmental fluctuations when nonlinear response functions are analyzed.
Ultrafast Energy Transfer in Excitonically Coupled Molecules Induced by a Nonlocal Peierls Phonon
(2019)
Molecular vibration can influence exciton transfer via either a local (intramolecular) Holstein or a nonlocal (intermolecular) Peierls mode. We show that a strong vibronic coupling to a nonlocal mode dramatically speeds up the transfer by opening an additional transfer channel. This Peierls channel is rooted in the formation of a conical intersection of the excitonic potential energy surfaces. For increasing Peierls coupling, the electronically coherent transfer for weak coupling turns into an incoherent transfer of a localized exciton through the intersection for strong coupling. The interpretation in terms of a conical intersection intuitively explains recent experiments of ultrafast energy transfer in photosynthetic and photovoltaic molecular systems.