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- Westfälisches Energieinstitut (32) (entfernen)
Alle Maßnahmen der Technischen Gebäudeausrüstung sollten daran gemessen werden, den Primär-energieverbrauch so gering wie möglich zu halten, dabei aber auch die geforderten Raumzustände während der Gebäude- und Anlagennutzung sicherzustellen.
Heute geplante Gebäude und deren RLT-Anlagen werden mit großer Wahrscheinlichkeit auch noch in 15 bis 20 Jahren in Betrieb sein, so dass lokale Klimaänderungen heute bereits mitgedacht und –geplant werden sollten. Die Testreferenzjahre des Deutschen Wetterdienstes bieten diese Möglichkeit mit lokalen Wetterdaten für die Bezugsjahre 2015 und 2045.
Am Beispiel eines Zentralluftgerätes einer Krankenhaus-Intensivstation wurde für die 15 Wetter¬stationen der VDI 4710, Blatt 3 in Deutschland untersucht, wie sich die Leistungsanforderungen von heute zum Jahr 2045 hin ändern werden und welche Konsequenzen sich daraus für die Planung ableiten lassen. Hierbei werden die Leistungen, Energieverbräuche und Betriebszeiten der einzelnen RLT-Komponenten analysiert und verglichen.
Darüber hinaus wurde erstmalig ein „Deutschlandwetter“ auf Basis der Regionen berechnet. Dieser Ansatz liefert die stündlichen Witterungsverhältnisse für das Bundesgebiet. Wenn diese Methode auf die tatsächlichen Wetterdaten der zurückliegenden Jahre angewandt wird, kann damit analog zum Wind- und Solarindex ein Heiz- bzw. Kühlindex beschrieben werden. Damit lassen sich Modellierungsansätze zur Beschreibung der Energiewende im Gebäudesektor deutlich verbessern.
Performance enhancing study for large scale PEM electrolyzer cells based on hydraulic compression
(2017)
This experimental work deals with the preparation and investigation of PEM fuel cell electrodes, which are obtained using Graphene Related Material (GRM) serving as catalyst support material for platinum nanoparticles. The applied GRM belong to the group of carbon nanofibers and exhibits a helical-ribbon structure with dimensions of 50 nm in diameter and an average length up to a few µm. Furthermore, utilized GRM provide a superior graphitisation degree of about 100 %, which leads to both high corrosion resistance and low ohmic resistance. Material stability plays one of the main roles for long term fuel cell operation, whereby a great electrical catalyst contact combined with high specific surface area yields in high fuel cell performances.
Prior to GRM dispersion and deposition onto a gas diffusion layer, the graphene structures are functionalized by oxygen plasma treatment. Through this step, functional oxygen groups are generated onto the GRM outer surface providing an improved hydrophilic behaviour and facilitating the GRM suspension preparation. In addition, the oxygen groups act as anchors for platinum nanoparticles which are subsequently deposited onto the GRM surface through a pulse electrodeposition process.
Membrane electrode assemblies produced with the prepared electrodes are investigated in-situ in a PEM fuel cell test bench.
This experimental work deals with the preparation and investigation of PEM fuel cell electrodes, which are obtained using Graphene Related Material (GRM) serving as catalyst support material for platinum nanoparticles. The applied GRM belong to the group of carbon nanofibers and exhibits a helical-ribbon structure with dimensions of 50 nm in diameter and an average length up to a few µm. Furthermore, utilized GRM provide a superior graphitisation degree of about 100 %, which leads to both high corrosion resistance and low ohmic resistance. Material stability plays one of the main roles for long term fuel cell operation, whereby a great electrical catalyst contact combined with high specific surface area yields in high fuel cell performances.
Prior to GRM dispersion and deposition onto a gas diffusion layer, the graphene structures are functionalized by oxygen plasma treatment. Through this step, functional oxygen groups are generated onto the GRM outer surface providing an improved hydrophilic behaviour and facilitating the GRM suspension preparation. In addition, the oxygen groups act as anchors for platinum nanoparticles which are subsequently deposited onto the GRM surface through a pulse electrodeposition process.
Membrane electrode assemblies produced with the prepared electrodes are investigated in-situ in a PEM fuel cell test bench.
To further increase platinum utilisation in PEM fuel cells CNFs are investigated as catalyst support material due to the CNF’s high specific surface area. Furthermore, CNFs provide suitable properties concerning corrosion resistance as well as electrical conductivity in contrast to conventional carbon supports.
This work presents the results of an electrode preparation procedure based on O2 plasma activated CNFs. The plasma treatment leads to CNF dispersibility in alcohol/water for a spray coating process. Furthermore, O2 plasma activation enhances metal deposition on the CNF’s surface. Pulse plating procedure as well as wet chemical metal synthesis have been used for particle deposition. For pulse plating a potentiostat/galvanostat type MMates 510 AC from Materials Mates, Italy has been used. Electrode morphology has been determined in SEM type XL 30 ESEM from Philips, The Netherlands.
An energy economy with high share of renewable but volatile energy sources is dependent on storage strategies in order to ensure sufficient energy delivery in periods of e.g. low wind and/or low solar radiation. Hydrogen as environmental friendly energy carrier is thought to be an appropriate solution for large scale energy storage. In 2011 the NOW (national organisation for hydrogen in Germany) calculated the demand for hydrogen energy systems as positive (0.8 GW to 5.25 GW) and negative supply for varying power demand (0.68 to 4.3 GW) for the German energy economy in 2025. Due to its dynamic behaviour on load changes polymer electrolyte membrane fuel cells (PEMFC) as well as water electrolyser systems (PEMEL) can play a significant role for large scale hydrogen based storage systems. In this work a novel design concept for modular fuel cell and electrolyser stacks is presented with single cells in pockets surrounded by a hydraulic medium. This hydraulic medium introduces necessary compression forces on the membrane electrode assembly (MEA) of each cell within a stack. Furthermore, ideal stack cooling is achieved by this medium. Due to its modularity and scalability the modular stack design with hydraulic compression meets the requirements for large PEMFC as well as PEMEL units. Small scale prototypes presented in this work illustrate the potential of this design concept.